(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxamide - Names and Identifiers
Name | (1S)-(-)-Camphanic acid amide
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Synonyms | (S)-(-)-CAMPHANIC ACID AMIDE (1S)-(-)-CAMPHANIC ACID AMIDE (1S)-(-)-Camphanic acid amide 4,7,7-trimethyl-3-bicyclo[2.2.1]heptanecarboxamide (1R,4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo2.2.1heptane-4-carboxamide (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxamide (1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxamide 2-oxabicyclo[2.2.1]heptane-1-carboxamide, 4,7,7-trimethyl-3-oxo-, (1S,4R)- 2-Oxabicyclo[2.2.1]heptane-1-carboxamide, 4,7,7-trimethyl-3-oxo-, (1S,4R)- (9CI)
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CAS | 54200-37-2
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InChI | InChI=1/C10H15NO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3,(H2,11,12)/t9-,10+/m0/s1 |
(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxamide - Physico-chemical Properties
Molecular Formula | C10H15NO3
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Molar Mass | 197.23 |
Density | 1.239g/cm3 |
Boling Point | 393.3°C at 760 mmHg |
Flash Point | 217.7°C |
Vapor Presure | 2.16E-06mmHg at 25°C |
Refractive Index | 1.533 |
(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxamide - Introduction
(1S)-(-)-Camphanic acid amide is a chiral compound with the chemical formula C10H17NO2. Its appearance is white crystalline powder. The following is an introduction to the nature, use, formulation and safety information of (1S)-(-)-Camphanic acid:
Nature:
-melting point: about 156-158 ℃
-Stable solid at room temperature
-Soluble in alcohol, ethers and chloroform, slightly soluble in water
-Has a camphor scent
Use:
- (1S)-(-)-Camphanic acid can be used as chiral catalyst in organic synthesis. It can effectively catalyze asymmetric organic chemical reactions, such as redox, carbonylation and so on.
Preparation Method:
- (1S)-(-)-Camphanic acid can be obtained by reacting (1S)-(-)-camphoric acid with an appropriate amine. The reaction may be carried out in a suitable solvent and an acidic catalyst is added to promote the reaction.
Safety Information:
- (1S)-(-)-Camphanic acid has no obvious safety hazard under normal use conditions.
-Because it is soluble in organic solvents and slightly soluble in water, care should be taken to avoid direct contact with skin and eyes during handling.
-May cause eye, respiratory or skin irritation when exposed or inhaled in large quantities.
Last Update:2024-04-10 22:29:15